My hot water tank (non mega flow) is heated morning and evening for set times and once the desired temperature is reached the system switches off. I doubt that in any system the boiler fires all day. If it were set to operate any time of the day it would fire intermittently as tank losses and water draw off lower the temperature of the stored water.. Similarly, in a combi I've seen them fire intermittently to maintain the internal mini tank temperature, so producing near instant hot water at nearby taps.
What you describe of using the immersion morning and evening is essentially the same as my practice. The headline price of electricity is nearly 5 times the price of gas, and I'd aimed off for boiler and pipework losses in stating 4 times as a rule of thumb.
Current Eon Next customer, ex EDF, Zog and Symbio. Don't think dual fuel saves money and think the smart meter programme is a waste of our money. Chronologically Gifted. If I offend let me know by private message, but I’ll continue to express my opinions nonetheless.